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Method
Detection Limits
POLYCYCLIC
AROMATIC HYDROCARBON METHOD DETECTION LIMITS
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Matrix:
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Water
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Sediment
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Fish tissue
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Oyster Tissue
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Amount of Sample:
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1 L
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15 g
|
6 g
|
15 g
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Final Extract Volume:
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1ml
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1ml
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0.5 ml
|
0.5 ml
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MDL (units):
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(ng/L)
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(ng/dry g)
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(ng/wet g)
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(ng/wet g)
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|
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Naphthalene
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9.45
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0.95
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0.75
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0.52
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C1-Naphthalenes
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7.60
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0.42
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1.16
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2.26
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C2-Naphthalenes
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4.47
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0.34
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1.46
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1.61
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C3-Naphthalenes
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4.47
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0.34
|
1.46
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1.61
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C4-Naphthalenes
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4.47
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0.34
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1.46
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1.61
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Biphenyl
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2.31
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0.30
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0.87
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0.31
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Acenaphthylene
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3.27
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0.17
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0.41
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0.24
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Acenaphthene
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2.22
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0.22
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0.51
|
0.31
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Fluorene
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2.33
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0.12
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0.50
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0.24
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C1-Fluorenes
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4.67
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0.24
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1.00
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0.47
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C2-Fluorenes
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4.67
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0.24
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1.00
|
0.47
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C3-Fluorenes
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4.67
|
0.24
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1.00
|
0.47
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Phenanthrene
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3.99
|
0.17
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0.56
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0.20
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Anthracene
|
2.02
|
0.15
|
0.38
|
0.19
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C1-Phenanthrenes/Anthracenes
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7.98
|
0.34
|
1.12
|
0.40
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C2-Phenanthrenes/Anthracenes
|
7.98
|
0.34
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1.12
|
0.40
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C3-Phenanthrenes/Anthracenes
|
7.98
|
0.34
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1.12
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0.40
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C4-Phenanthrenes/Anthracenes
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7.98
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0.34
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1.12
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0.40
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Dibenzothiophene
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3.29
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0.16
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0.40
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0.17
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C1-Dibenzothiophenes
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6.58
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0.31
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0.79
|
0.34
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C2-Dibenzothiophenes
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6.58
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0.31
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0.79
|
0.34
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C3-Dibenzothiophenes
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6.58
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0.31
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0.79
|
0.34
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Fluoranthene
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3.17
|
0.31
|
0.50
|
0.28
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Pyrene
|
2.86
|
0.49
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0.44
|
0.13
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C1-Fluoranthene/Pyrene
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6.34
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0.61
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1.00
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0.56
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C2-Flouranthene/Pyrene
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6.34
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0.61
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1.00
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0.56
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C2-Flouranthene/Pyrene
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6.34
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0.61
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1.00
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0.56
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Naphthobenzothiphene
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3.99
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0.17
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0.56
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0.20
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C1-Naphthobenzothiophene
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7.98
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0.34
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1.12
|
0.40
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C2-Naphthobenzothiophene
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7.98
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0.34
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1.12
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0.40
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C3-Naphthobenzothiophene
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7.98
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0.34
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1.12
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0.40
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Benz(a)anthracene
|
1.15
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0.18
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0.21
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0.24
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Chrysene
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1.14
|
0.24
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0.32
|
0.59
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C1-Chrysenes
|
2.28
|
0.48
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0.65
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1.18
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C2-Chrysenes
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2.28
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0.48
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0.65
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1.18
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C3-Chrysenes
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2.28
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0.48
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0.65
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1.18
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C4-Chrysenes
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2.28
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0.48
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0.65
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1.18
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Benzo(b)fluoranthene
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2.25
|
0.26
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0.69
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0.26
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Benzo(k)fluoranthene
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3.13
|
0.28
|
0.58
|
0.28
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Benzo(e)pyrene
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3.66
|
0.24
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0.91
|
0.16
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Benzo(a)pyrene
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3.05
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0.25
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0.40
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0.16
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Perylene
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1.42
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0.18
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1.05
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1.00
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Indeno(1,2,3-c,d)pyrene
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2.47
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0.30
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0.87
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0.31
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Dibenzo(a,h)anthracene
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1.84
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0.21
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0.41
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0.20
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C1-Dibenzo(a,h)anthracene
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3.68
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0.41
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0.82
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0.40
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C2-Dibenzo(a,h)anthracene
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3.68
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0.41
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0.82
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0.40
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C3-Dibenzo(a,h)anthracene
|
3.68
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0.41
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0.82
|
0.40
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Benzo(g,h,i)perylene
|
2.44
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0.34
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0.29
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0.16
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Individual Isomers
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|
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2-Methylnaphthalene
|
3.99
|
0.24
|
0.65
|
1.47
|
1-Methylnaphthalene
|
3.61
|
0.18
|
0.51
|
0.79
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2,6-Dimethylnaphthalene
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2.24
|
0.17
|
0.73
|
0.81
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1,6,7 Trimethylnaphthalene
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1.91
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0.15
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0.68
|
0.26
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1-Methylphenanthrene
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7.63
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0.17
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0.65
|
0.33
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CHLORINATED
HYDROCARBON METHOD DETECTION LIMITS
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Matrix:
|
Sediment
|
Water
|
Fish Tissue
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Amount of Sample:
|
15g dried
|
1 L
|
6 g wet
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Final Extract Volume:
|
1 mL
|
1 mL
|
0.5 mL
|
MDL (units):
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(ng/dry g)
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(ng/L)
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(ng/wet g)
|
|
Aldrin
|
0.07
|
0.64
|
0.45
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Dieldrin
|
0.06
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1.49
|
1.66
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Endrin
|
0.06
|
0.72
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0.91
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Heptachlor
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0.06
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0.75
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0.15
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Heptachlor-Epoxide
|
0.08
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0.64
|
0.60
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Oxychlordane
|
0.07
|
0.29
|
0.91
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Alpha-Chlordane
|
0.06
|
0.52
|
0.45
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Gamma-Chlordane
|
0.06
|
0.84
|
0.60
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Trans-Nonachlor
|
0.06
|
2.54
|
0.45
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Cis-Nonachlor
|
0.07
|
0.63
|
0.15
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Alpha-HCH
|
0.12
|
0.84
|
0.30
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Beta-HCH
|
0.06
|
1.95
|
0.45
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Delta-HCH
|
0.06
|
1.41
|
0.45
|
Gamma-HCH
|
0.05
|
0.46
|
0.45
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2,4'-DDD
|
0.05
|
1.03
|
0.45
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4,4'-DDD
|
0.08
|
0.59
|
0.45
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2,4'-DDE
|
0.06
|
0.82
|
0.60
|
4,4'-DDE
|
0.06
|
0.98
|
0.91
|
2,4'-DDT
|
0.09
|
2.44
|
0.30
|
4,4'-DDT
|
0.06
|
2.44
|
0.91
|
Hexachlorobenzene
|
0.07
|
0.90
|
0.15
|
Endosulfan II
|
0.06
|
2.44
|
1.21
|
Mirex
|
0.07
|
1.77
|
0.30
|
Chlorpyrifos
|
0.08
|
0.96
|
0.15
|
|
|
|
|
PCB8/5
|
0.12
|
0.96
|
0.75
|
PCB18
|
0.05
|
0.99
|
0.45
|
PCB28
|
0.08
|
0.99
|
0.60
|
PCB29
|
0.06
|
1.12
|
0.45
|
PCB44
|
0.06
|
0.96
|
0.75
|
PCB52
|
0.05
|
1.00
|
0.45
|
PCB66/80
|
0.05
|
4.83
|
0.60
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PCB87/115
|
0.09
|
1.00
|
0.60
|
PCB101/90
|
0.07
|
1.00
|
0.75
|
PCB105
|
0.08
|
1.24
|
0.30
|
PCB118
|
0.08
|
1.00
|
1.51
|
PCB128
|
0.05
|
1.00
|
3.32
|
PCB138/160
|
0.12
|
4.46
|
0.75
|
PCB153/132/168
|
0.07
|
0.96
|
1.06
|
PCB170/190
|
0.12
|
0.96
|
0.91
|
PCB180
|
0.10
|
0.96
|
0.15
|
PCB187
|
0.10
|
0.96
|
0.45
|
PCB195/208
|
0.10
|
0.96
|
0.15
|
PCB201/157
|
0.09
|
1.15
|
0.15
|
PCB206
|
0.10
|
1.15
|
0.15
|
PCB209
|
0.14
|
1.15
|
0.15
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BUTLYTIN
METHOD DETECTION LIMITS
|
Matrix:
|
Sediment
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Water
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Oyster Tissue
|
Amount of Sample:
|
15g dried
|
1 L
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10 g
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Final Extract Volume:
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10 mL
|
10 mL
|
10 mL
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MDL (units):
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(ng Sn/g dry)
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(ng Sn/mL)
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(ng Sn/g wet)
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Monobutyltin
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0.224
|
0.010
|
0.174
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Dibutyltin
|
0.292
|
0.012
|
0.539
|
Endrin
|
0.370
|
0.009
|
1.311
|
Tributyltin
|
0.434
|
0.007
|
0.763
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